The Tchaikovsky disc I recommended earlier was out of a boxed set of 10 'Master Recordings' by Herbert von Karajan. Having played over half of them now, I can confidently recommend the whole box. I've just finished listening to the ravishingly mellifluous violin tone of the young Anne-Sophie Mutter in Beethoven's Violin Concerto, recorded in 1979, another disc in this set.
http://www.amazon.com/Herbert-von-Karajan-Recordings-Digital/dp/B000W99II4/
http://www.amazon.com/Herbert-von-Karajan-Recordings-Digital/dp/B000W99II4/