We can measure the electronics and reproducers and pickups but that is only by comparing what they are told to do against what they actually do and examine the differences in various ways.
If one chose to take the ultra pure position, one could say nothing is perfect, everything has flaws.
In reality or to be realistic, one has to take into account the relative situation.
For example, at the purist level with no context, the best telescope mirror is a mountain range of atomic level irregularity.
To the eye, it is perfectly smooth, to the telescope maker it is within 1 /10 wavelength of light in the spectrum it’s made for, technical perfection.
From that approach it is not simple but possible to reduce all the errors in the electronic chain to "very small" levels.
All of this falls apart when you attach speakers, all, even the best alter the signal in many ways and then the room returns many later reflected signals arriving after the main /direct one.
Past that is the issue that how you hear is a subjective phenomena while every aspect of measurement is quantifying properties.
Lastly and a real turd in the punch bowl for realism is that there are VERY few ways to actually capture a realistic live / real stereo image.
Most recordings use panning and other acoustic tricks to place various sounds in the panorama, they are a mostly a simulation of a live event.
I don’t know if you make things or experiment, if you do and have some coins to do this, try this experiment.
If you don’t have a decent USB pre-amp, get something like am M-audio fast track pro or similar.
This allows you to record and play two channels up to 24/96K with low distortion AND has two decent mic pre-amps.
Obtain a measurement microphone (get two if you can) look at speaker building sites like Madisound or more costly ones from Earthworks, B&K, etc.
Now set up one channel and record things around your home, listen through headphones (same signal on both R and L).
If you don’t have a sound recording program Audacity is free.
Now, when you play back the one channel through one speaker, you will have a pretty good reproduction, the vast majority of the error being your speakers and the room interaction.
During nice weather, you can hear what your speakers actually sound like by themselves by listening outdoors.
If you enjoy it, there are forums and such which further open the door.
I mostly work on reproducers, but capture is a keen interest. I have devised an alternative way of capturing that image.
This is still in the R&D stage and not so exciting but give this a try with headphones.
This would be the forward facing image pair (I have a 6 channel, 360 degree plus overhead image version in parts coming along)
http://www.danleysoundlabs.com/TrainStart.wav
Please do consider recording yourself, for less than one might think you can make enjoyable recordings, experiment and unlike an open ended evaluation, if you were there when it was recorded, you really do know what it sounded like live.
Best,
Tom